Chamber neck diameter is half the reason to make a pound cast (beautiful work, by the way). Measure the OD of the pound cast in the are where the bullet body would be seated. That will tell you what your chamber neck diameter is.
Step two is determine case wall thickness (sometimes a little tricky). Remove any burrs or bellmouth or crimp from a fired case and measure the wall thickness of the brass.
Step three is subtract two times your wall thickness from your chamber neck diameter, then subtract another thousandth for clearance, and the result will be the largest bullet your rifle will safely chamber.
Due to brass spring-back after firing, your fired brass should be about the diameter that you want your loaded brass to be, because the clearance will be established by the spring-back. So you can measure a fired case's ID along the length where the bullet is seated and that will be pretty close to the size you want to make your bullets.
REDUCE THE TOLERANCE STACKING. You want your loaded cartridge to fit close to the chamber walls so your bullet doesn't get crooked on firing. Make sense? Crooked bullets don't fly straight. Due to your chamber and bullet design, you will have to guide that bullet straight by minimizing the tolerances in the CHAMBER. Bore and groove measurements are entirely meaningless here, so forget about them.
Next post I will put up an illustration I just made showing the tolerance I'm trying to get you to measure and reduces here, and show you WHY you need to do that to get better accuracy. Bore/groove have no bearing on how you best fit the bullet to the rifle in this instance, you simply want to put the largest-diameter bullet that you possibly can in this rifle.